A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh) 2 Mo(μ‐CO) 2 (CO)} 2 (S 2 C 6 H 2 S 2 ) 2 ] with Two π‐Conjugated S 2 C 6 S 2  Bridges: Synthesis, Crystal Structure, and Properties | Zendy

Zhu BaoHua | Zendy; Shibata Yusuke | Zendy; Muratsugu Satoshi | Zendy; Yamanoi Yoshinori | Zendy; Nishihara Hiroshi | Zendy

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A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh) 2 Mo(μ‐CO) 2 (CO)} 2 (S 2 C 6 H 2 S 2 ) 2 ] with Two π‐Conjugated S 2 C 6 S 2 Bridges: Synthesis, Crystal Structure, and Properties

Author(s) -

Zhu BaoHua,

Shibata Yusuke,

Muratsugu Satoshi,

Yamanoi Yoshinori,

Nishihara Hiroshi

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200900509

Subject(s) - crystallography , cluster (spacecraft) , metal , chemistry , rhodium , electron counting , electron , physics , computer science , catalysis , organic chemistry , programming language , biochemistry , quantum mechanics

Two dragons playing ball : Direct metal–metal bond formation using a π‐conjugated dinuclear metalladithiolene complex with two electron‐deficient metal centers as building blocks led to a cyclic double trinuclear heterometalladithiolene cluster with two parallel plane bridges (see structure; Rh pink, Mo green, S yellow, C gray, O red).

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