Premium
A Cyclic Hexanuclear Heterometalladithiolene Cluster [{(Cp*Rh) 2 Mo(μ‐CO) 2 (CO)} 2 (S 2 C 6 H 2 S 2 ) 2 ] with Two π‐Conjugated S 2 C 6 S 2 Bridges: Synthesis, Crystal Structure, and Properties
Author(s) -
Zhu BaoHua,
Shibata Yusuke,
Muratsugu Satoshi,
Yamanoi Yoshinori,
Nishihara Hiroshi
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900509
Subject(s) - crystallography , cluster (spacecraft) , metal , chemistry , rhodium , electron counting , electron , physics , computer science , catalysis , organic chemistry , programming language , biochemistry , quantum mechanics
Two dragons playing ball : Direct metal–metal bond formation using a π‐conjugated dinuclear metalladithiolene complex with two electron‐deficient metal centers as building blocks led to a cyclic double trinuclear heterometalladithiolene cluster with two parallel plane bridges (see structure; Rh pink, Mo green, S yellow, C gray, O red).