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Devising Boron Reagents for Orthogonal Functionalization through Suzuki–Miyaura Cross‐Coupling
Author(s) -
Tobisu Mamoru,
Chatani Naoto
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900465
Subject(s) - moiety , reagent , boron , surface modification , reactivity (psychology) , coupling reaction , combinatorial chemistry , chemistry , coupling (piping) , polymer chemistry , organic chemistry , materials science , catalysis , medicine , alternative medicine , pathology , metallurgy
Seeing the sites : The Suzuki–Miyaura reaction of substrates containing multiple coupling sites has been performed in a directed manner through the reactivity modulation of the boron moiety (see scheme). Several other strategies are also discussed.