Premium
Structure and Reactivity of a Unique Y‐Shaped Tricoordinate Bis(silyl)platinum(II)–NHC Complex
Author(s) -
BerthonGelloz Guillaume,
de Bruin Bas,
Tinant Bernard,
Markó István E.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900435
Subject(s) - platinum , silylation , reactivity (psychology) , chemistry , crystallography , stereochemistry , catalysis , organic chemistry , medicine , alternative medicine , pathology
Y not? A unique, three‐coordinate Y‐shaped bis(silyl)platinum(II) complex was isolated and characterized (see structure; C light gray, N blue, Si pink, Pt dark gray). DFT studies on a model system shed light on the nature of this unusual coordination mode for platinum(II).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom