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A p‐Type NiO‐Based Dye‐Sensitized Solar Cell with an Open‐Circuit Voltage of 0.35 V
Author(s) -
Gibson Elizabeth A.,
Smeigh Amanda L.,
Le Pleux Loïc,
Fortage Jérôme,
Boschloo Gerrit,
Blart Errol,
Pellegrin Yann,
Odobel Fabrice,
Hagfeldt Anders,
Hammarström Leif
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900423
Subject(s) - non blocking i/o , tandem , open circuit voltage , materials science , solar cell , electrolyte , dye sensitized solar cell , voltage , optoelectronics , cobalt , valence band , electrode , band gap , analytical chemistry (journal) , chemistry , electrical engineering , catalysis , metallurgy , chromatography , engineering , composite material , biochemistry
In tandem : Employing a molecular dyad and a cobalt‐based electrolyte gives a threefold‐increase in open‐circuit voltage ( V OC ) for a p‐type NiO device ( V OC =0.35 V), and a fourfold better energy conversion efficiency. Incorporating these improvements in a TiO 2 /NiO tandem dye‐sensitized solar cell (TDSC), results in a TDSC with a V OC =0.91 V (see figure; CB=conductance band, VB= valence band).

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