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Spin‐Polarized Structures and Solid‐State NMR Spectroscopy of Paramagnetic Compounds
Author(s) -
Schmedt auf der Günne Jörn
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200900360
Subject(s) - paramagnetism , hyperfine structure , spectroscopy , relaxation (psychology) , nuclear magnetic resonance spectroscopy , solid state nuclear magnetic resonance , spin (aerodynamics) , hyperfine coupling , solid state , transverse relaxation optimized spectroscopy , chemistry , electronic structure , condensed matter physics , chemical physics , materials science , nuclear magnetic resonance , fluorine 19 nmr , computational chemistry , physics , atomic physics , quantum mechanics , psychology , social psychology , thermodynamics
On an atomic scale and with high sensitivity, solid‐state NMR spectroscopy can provide information about the electronic spin density and coupling mechanisms in paramagnetic compounds. The picture shows how the hyperfine splitting collapses through relaxation. Insights into which compounds are suitable and which approximations have to be made are given.