A Spherical Molecule with a Carbon‐Free  I  h ‐C 80  Topological Framework | Zendy

Scheer Manfred | Zendy; Schindler Andrea | Zendy; Gröger Christian | Zendy; Virovets Alexander V. | Zendy; Peresypkina Eugenia V. | Zendy

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A Spherical Molecule with a Carbon‐Free I h ‐C 80 Topological Framework

Author(s) -

Scheer Manfred,

Schindler Andrea,

Gröger Christian,

Virovets Alexander V.,

Peresypkina Eugenia V.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200900342

Subject(s) - icosahedral symmetry , supermolecule , fullerene , molecule , topology (electrical circuits) , crystallography , physics , chemistry , materials science , combinatorics , quantum mechanics , mathematics

The complete encapsulation of ortho ‐carborane by a fullerene‐like building‐block system consisting of pentaphosphaferrocene and Cu I Cl leads to the formation of the spherical supermolecule C 2 B 10 H 12 §[{Cp*Fe(η 5 ‐P 5 )} 12 (CuCl) 20 ]. This product of template‐controlled aggregation represents the first example of a carbon‐free C 80 analogue possessing icosahedral symmetry.

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