Structural Characterization and Remarkable Axial Ligand Effect on the Nucleophilic Reactivity of a Nonheme Manganese(III)–Peroxo Complex | Zendy

Annaraj Jamespandi | Zendy; Cho Jaeheung | Zendy; Lee YongMin | Zendy; Kim Sung Yeon | Zendy; Latifi Reza | Zendy; de Visser Sam P. | Zendy; Nam Wonwoo | Zendy

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Structural Characterization and Remarkable Axial Ligand Effect on the Nucleophilic Reactivity of a Nonheme Manganese(III)–Peroxo Complex

Author(s) -

Annaraj Jamespandi,

Cho Jaeheung,

Lee YongMin,

Kim Sung Yeon,

Latifi Reza,

de Visser Sam P.,

Nam Wonwoo

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200900118

Subject(s) - reactivity (psychology) , ligand (biochemistry) , manganese , nucleophile , chemistry , stereochemistry , medicinal chemistry , organic chemistry , receptor , catalysis , medicine , biochemistry , alternative medicine , pathology

The dark side of the Mn : A manganese(III) complex bearing a 13‐membered macrocyclic ligand ( 1 , see picture) binds a peroxo ligand in a side‐on η 2 fashion. The reactivity of 1 is influenced by the introduction of anionic ligands trans to the peroxo group. Electronic and structural changes upon trans ‐ligand binding explain the increased nucleophilicity of the resulting complexes 1 ‐X.

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