A Ditopic Ion‐Pair Receptor Based on Stacked Nucleobase Quartets | Zendy

van der Wijst Tushar | Zendy; Fonseca Guerra Célia | Zendy; Swart Marcel | Zendy; Bickelhaupt F. Matthias | Zendy; Lippert Bernhard | Zendy

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A Ditopic Ion‐Pair Receptor Based on Stacked Nucleobase Quartets

Author(s) -

van der Wijst Tushar,

Fonseca Guerra Célia,

Swart Marcel,

Bickelhaupt F. Matthias,

Lippert Bernhard

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200900057

Subject(s) - nucleobase , guanine , stacking , aqueous solution , chemistry , ion , salt (chemistry) , computation , stereochemistry , crystallography , algorithm , dna , biochemistry , computer science , organic chemistry , nucleotide , gene

Pass the salt, please! State‐of‐the‐art computations indicate that the stacking complex of a guanine quartet and an adenine quartet (G 4 A 4 ) can function as a potent ditopic receptor for NaCl in aqueous solution (see picture; Na + , Cl − yellow, O red, N blue, C black, H white).

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