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Inside Cover: Unmasking Representative Structures of TMP‐Active Hauser and Turbo‐Hauser Bases (Angew. Chem. Int. Ed. 42/2008)
Author(s) -
GarcíaÁlvarez Pablo,
Graham David V.,
Hevia Eva,
Kennedy Alan R.,
Klett Jan,
Mulvey Robert E.,
O'Hara Charles T.,
Weatherstone Susan
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200890208
Subject(s) - regioselectivity , chemistry , aryl , int , reagent , combinatorial chemistry , surface modification , cover (algebra) , stereochemistry , organic chemistry , computer science , catalysis , engineering , programming language , mechanical engineering , alkyl
The molecular engines that drive enhanced magnesium–hydrogen exchange reactions are revealed by R. E. Mulvey and co‐workers in their Communication on page 8079 ff. with the structure elucidation of a 2,2,6,6‐tetramethylpiperidide Hauser base and its recently reported updated turbo model. These bases have become key reagents for the regioselective functionalization of a wide variety of aryl, heteroaryl, and metallocenyl compounds.