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Cover Picture: Reversible Redox Reactions in an Extended Polyoxometalate Framework Solid (Angew. Chem. Int. Ed. 36/2008)
Author(s) -
Ritchie Chris,
Streb Carsten,
Thiel Johannes,
Mitchell Scott G.,
Miras Haralampos N.,
Long DeLiang,
Boyd Thomas,
Peacock Robert D.,
McGlone Thomas,
Cronin Leroy
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200890175
Subject(s) - redox , cover (algebra) , polyoxometalate , manganese , reagent , electron transfer , chemistry , int , materials science , nanotechnology , photochemistry , inorganic chemistry , computer science , catalysis , organic chemistry , engineering , operating system , mechanical engineering
Like a revolving door that can easily open, close, and return to the start, the first framework material that can undergo reversible electron‐transfer reactions is described by L. Cronin et al. in their Communication on page 6881 ff. The solid contains large pockets in which the redox reagents can reside; the manganese(II)/(III)‐containing framework is able to move between these oxidation states and is the first in a new class of redox solids.