Cover Picture: Pd II ‐Catalyzed Enantioselective Activation of C(sp 2 )H and C(sp 3 )H Bonds Using Monoprotected Amino Acids as Chiral Ligands (Angew. Chem. Int. Ed. 26/2008) | Zendy

Shi BingFeng | Zendy; Maugel Nathan | Zendy; Zhang YangHui | Zendy; Yu JinQuan | Zendy

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Cover Picture: Pd II ‐Catalyzed Enantioselective Activation of C(sp 2 )H and C(sp 3 )H Bonds Using Monoprotected Amino Acids as Chiral Ligands (Angew. Chem. Int. Ed. 26/2008)

Author(s) -

Shi BingFeng,

Maugel Nathan,

Zhang YangHui,

Yu JinQuan

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200890122

Subject(s) - enantioselective synthesis , palladium , catalysis , chemistry , alkylation , medicinal chemistry , stereochemistry , asymmetric carbon , nitrogen atom , amino acid , organic chemistry , ring (chemistry) , optically active , biochemistry

Gearing between the α carbon atom and the nitrogen atom of an amino acid relays chiral information to the palladium(II) center, which cleaves CH bonds asymmetrically. In their Communication on page 4882 ff. , J.‐Q. Yu et al. report on the palladium(II)‐catalyzed enantioselective alkylation of sp 2 and sp 3 CH bonds with boronic acids.

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