z-logo
Premium
Inside Cover: Toroidal Nanoobjects from Rosette Assemblies of Melamine‐Linked Oligo( p ‐phenyleneethynylene)s and Cyanurates (Angew. Chem. Int. Ed. 25/2008)
Author(s) -
Yagai Shiki,
Mahesh Sankarapillai,
Kikkawa Yoshihiro,
Unoike Kanako,
Karatsu Takashi,
Kitamura Akihide,
Ajayaghosh Ayyappanpillai
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Reports
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200890118
Subject(s) - supramolecular chemistry , rosette (schizont appearance) , toroid , materials science , melamine , self assembly , crystallography , ring (chemistry) , polymer chemistry , nanotechnology , polymer science , chemistry , composite material , physics , organic chemistry , crystal structure , plasma , quantum mechanics , immunology , biology
Nanodonuts form from hierarchical self‐organization of a melamine featuring π‐conjugated oligo(para‐phenyleneethynylene)s with a cyanurate. The toroidal nanostructures, with a diameter of 40 nm (see AFM image), form in decane under dilute conditions. S. Yagai, A. Ajayaghosh et al. propose in their Communication on page 4691 ff . that a hydrogen‐bonded rosette is an essential intermediate supramolecular species for such a hierarchical self‐organization process. The background picture shows a “bubble ring” made by a scuba diver.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here
Accelerating Research

Address

John Eccles House
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom