Inside Cover: Total Synthesis of (±)‐Axinellamines A and B (Angew. Chem. Int. Ed. 19/2008) | Zendy

O'Malley Daniel P. | Zendy; Yamaguchi Junichiro | Zendy; Young Ian S. | Zendy; Seiple Ian B. | Zendy; Baran Phil S. | Zendy

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Inside Cover: Total Synthesis of (±)‐Axinellamines A and B (Angew. Chem. Int. Ed. 19/2008)

Author(s) -

O'Malley Daniel P.,

Yamaguchi Junichiro,

Young Ian S.,

Seiple Ian B.,

Baran Phil S.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Reports

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200890085

Subject(s) - total synthesis , pyrrole , cover (algebra) , imidazole , int , amine gas treating , chemistry , class (philosophy) , combinatorial chemistry , stereochemistry , computer science , organic chemistry , engineering , programming language , mechanical engineering , artificial intelligence

Chemoselective by design is the total synthesis of marine pyrrole–imidazole alkaloids of the axinellamine/palau'amine/massadine class described by P. S. Baran and co‐workers in their Communication on page 3581 ff. Their approach features unconventional transformations on completely unprotected polyamino and hydroxylated substrates and a new method for chemoselective oxidations in such settings.

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