Discovery of Heteroatom‐“Embedded” Te⊂{W 18 O 54 } Nanofunctional Polyoxometalates by Use of Cryospray Mass Spectrometry | Zendy

Yan Jun | Zendy; Long DeLiang | Zendy; Wilson Elizabeth F. | Zendy; Cronin Leroy | Zendy

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Discovery of Heteroatom‐“Embedded” Te⊂{W 18 O 54 } Nanofunctional Polyoxometalates by Use of Cryospray Mass Spectrometry

Author(s) -

Yan Jun,

Long DeLiang,

Wilson Elizabeth F.,

Cronin Leroy

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200806343

Subject(s) - heteroatom , tellurium , cluster (spacecraft) , crystallography , chemistry , mass spectrometry , redox , analytical chemistry (journal) , inorganic chemistry , organic chemistry , ring (chemistry) , chromatography , computer science , programming language

The cryo game : Heteroatom‐embedded nanofunctional clusters are described that incorporate a [Te VI O 6 ] 6− species contained within a {W 18 O 54 } cage. Not only does the tellurium‐based species activate the {W 18 O 54 } cluster surface for assembly of larger nanoscale structures, such as [H 10 Te VI 2 W 58 O 198 ] 26− , it also undergoes a redox transformation inside the cluster from [Te VI O 6 ] 6− to [Te IV O 3 ] 2− .

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