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Grafting of Polyfluorene by Surface‐Initiated Suzuki Polycondensation
Author(s) -
Beryozkina Tetyana,
Boyko Ksenia,
Khanduyeva Natalya,
Senkovskyy Volodymyr,
Horecha Marta,
Oertel Ulrich,
Simon Frank,
Stamm Manfred,
Kiriy Anton
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200806217
Subject(s) - polyfluorene , condensation polymer , grafting , fluorene , palladium , materials science , polymer chemistry , suzuki reaction , polymer , chemical engineering , copolymer , catalysis , chemistry , organic chemistry , composite material , engineering
Graft work : The first surface‐initiated and site‐specific palladium‐catalyzed Suzuki polycondensation that allows selective grafting and patterning of semiconducting and emissive poly[9,9‐bis(2‐ethylhexyl)fluorene] ( 1 ) at room temperature is developed (see scheme). The pattering is demonstrated by AFM (see image).