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Rational Construction of 2D and 3D Borromean Arrayed Organic Crystals by Hydrogen‐Bond‐Directed Self‐Assembly
Author(s) -
Men YongBiao,
Sun Junliang,
Huang ZhiTang,
Zheng QiYu
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200806198
Subject(s) - hydrogen bond , adamantane , molecule , methanol , chemistry , trigonal crystal system , crystallography , crystal structure , organic chemistry
Borromean organic networks: The rigid and trigonal pyramidal molecule, 1,3,5‐tris(4‐carboxyphenyl)adamantane (TCA), self‐assembles into a 2D Borromean linked network by hydrogen bonds. Different linkers (methanol, phenazine, 4,4′‐bipyridine, and 4,4′‐azopyridine) result in more complex Borromean networks or a 3D polycatenation network.