The Antimony‐Based Type I Clathrate Compounds Cs 8 Cd 18 Sb 28  and Cs 8 Zn 18 Sb 28 | Zendy

Liu Yi | Zendy; Wu LiMing | Zendy; Li LongHua | Zendy; Du ShaoWu | Zendy; Corbett John D. | Zendy; Chen Ling | Zendy

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The Antimony‐Based Type I Clathrate Compounds Cs 8 Cd 18 Sb 28 and Cs 8 Zn 18 Sb 28

Author(s) -

Liu Yi,

Wu LiMing,

Li LongHua,

Du ShaoWu,

Corbett John D.,

Chen Ling

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200806158

Subject(s) - antimony , stoichiometry , diamagnetism , zintl phase , crystallography , phase (matter) , chemistry , clathrate hydrate , space group , materials science , inorganic chemistry , crystal structure , physics , x ray crystallography , hydrate , diffraction , organic chemistry , quantum mechanics , magnetic field , optics

In phase : The title compounds lie in a new region of phase space for such a structure, and have stoichiometries in accord with a classical Zintl phase formulation. The small semiconductor gaps indicated by DFT calculations are also supported by their diamagnetic susceptibilities.

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