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Giant Pores in a Chromium 2,6‐Naphthalenedicarboxylate Open‐Framework Structure with MIL‐101 Topology
Author(s) -
Sonnauer Andreas,
Hoffmann Frank,
Fröba Michael,
Kienle Lorenz,
Duppel Viola,
Thommes Matthias,
Serre Christian,
Férey Gérard,
Stock Norbert
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805980
Subject(s) - microcrystalline , sorption , mesoporous material , topology (electrical circuits) , materials science , crystallography , chemical engineering , chromium , chemistry , catalysis , organic chemistry , adsorption , metallurgy , mathematics , combinatorics , engineering
Large, larger, … Replacement of 1,4‐benzenedicarboxylate by 2,6‐naphthalenedicarboxylate in the MIL‐101 structure leads to an isoreticular mesoporous framework containing cages with diameters of 39 and 46 Å. High‐throughput methods are employed to determine appropriate reaction conditions. The microcrystalline compound is characterized by molecular simulation techniques, powder X‐ray diffraction, N 2 ‐sorption, and TEM investigations.