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Universal Scaffold for Fluorescent Conjugated Organoborane Polymers
Author(s) -
Li Haiyan,
Jäkle Frieder
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805863
Subject(s) - polymer , conjugated system , fluorescence , thermal stability , scaffold , luminescence , materials science , nucleophile , combinatorial chemistry , nanotechnology , photochemistry , chemistry , polymer chemistry , organic chemistry , optoelectronics , computer science , catalysis , physics , quantum mechanics , database
Pimp my polymer : A new versatile and strongly emissive conjugated polymer scaffold results when nucleophiles replace the labile bromine atoms on the fluorenylborane polymer backbone (see picture). Such modification allows facile tuning of the stability, thermal characteristics, and photophysical behavior of a diverse range of luminescent polymers with interesting optoelectronic properties and anion‐binding behavior.