A Dinuclear Nickel(I) Dinitrogen Complex and its Reduction in Single‐Electron Steps | Zendy

Pfirrmann Stefan | Zendy; Limberg Christian | Zendy; Herwig Christian | Zendy; Stößer Reinhard | Zendy; Ziemer Burkhard | Zendy

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A Dinuclear Nickel(I) Dinitrogen Complex and its Reduction in Single‐Electron Steps

Author(s) -

Pfirrmann Stefan,

Limberg Christian,

Herwig Christian,

Stößer Reinhard,

Ziemer Burkhard

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805862

Subject(s) - nickel , reduction (mathematics) , electron , chemistry , one electron reduction , combinatorial chemistry , materials science , computational chemistry , physics , electrochemistry , organic chemistry , mathematics , nuclear physics , geometry , electrode

Electron by electron : β‐Diketiminato nickel(I) complex fragments are capable of activating N 2 through coordination. The resulting complex can be reduced in two single‐electron steps, which further activates the NN bond. The picture shows the structure of the singly reduced complex with μ‐η 1 :η 1 ‐bound N 2 .

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