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First Higher‐Order Photocycloaddition to a CN Bond: 1,3‐Diazepines from Maleimides
Author(s) -
Cubbage Kara L.,
OrrEwing Andrew J.,
BookerMilburn Kevin I.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805846
Subject(s) - chemistry , order (exchange) , business , finance
A light touch is all that is required to cleave a maleimide CN bond to effect a [5+2] photocycloaddition with a sterically encumbered CN moiety (see scheme).