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Synthesis of Orthorhombic Mo‐V‐Sb Oxide Species by Assembly of Pentagonal Mo 6 O 21 Polyoxometalate Building Blocks
Author(s) -
Sadakane Masahiro,
Yamagata Keiko,
Kodato Katsunori,
Endo Keisuke,
Toriumi Koshiro,
Ozawa Yoshiki,
Ozeki Tomoji,
Nagai Takuro,
Matsui Yoshio,
Sakaguchi Norihito,
Pyrz William D.,
Buttrey Douglas J.,
Blom Douglas A.,
Vogt Thomas,
Ueda Wataru
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805792
Subject(s) - orthorhombic crystal system , polyoxometalate , crystallography , oxide , materials science , ion , pentagonal bipyramidal molecular geometry , crystal structure , phase (matter) , catalysis , inorganic chemistry , chemistry , metallurgy , organic chemistry
Mix and match : The pentagonal [Mo 6 O 21 ] n − polyoxomolybdate building block assembles with other sources of Mo, V, and Sb ions to form an orthorhombic Mo‐V‐Sb oxide. The first single‐crystal X‐ray analysis of an orthorhombic Mo–V‐based oxide, a promising catalyst for light alkane selective oxidation known as the “M1 phase”, revealed the structure of the compound.