Exploiting the Divergent Reactivity of Aryl–Palladium Intermediates for the Rapid Assembly of Fluorene and Phenanthrene Derivatives | Zendy

Zhao YaBin | Zendy; Mariampillai Brian | Zendy; Candito David A. | Zendy; Laleu Benoît | Zendy; Li Mengzhou | Zendy; Lautens Mark | Zendy

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Exploiting the Divergent Reactivity of Aryl–Palladium Intermediates for the Rapid Assembly of Fluorene and Phenanthrene Derivatives

Author(s) -

Zhao YaBin,

Mariampillai Brian,

Candito David A.,

Laleu Benoît,

Li Mengzhou,

Lautens Mark

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805780

Subject(s) - fluorene , phenanthrene , reactivity (psychology) , palladium , domino , aryl , chemistry , combinatorial chemistry , photochemistry , organic chemistry , catalysis , medicine , alkyl , alternative medicine , pathology , polymer

They all fall down : The value of domino processes can be greatly enhanced when the possibility exists for one to selectively diverge from a common intermediate. In preliminary studies the dual reactivity of aryl–palladium intermediates is exploited. A diverse array of fluorene and phenanthrene derivatives were synthesized in a rapid and efficient manner (see scheme).

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