[2,6‐(Trip) 2 H 3 C 6  ](Cp*)Si: A Stable Monomeric Arylsilicon(II) Compound | Zendy

Jutzi Peter | Zendy; Leszczyńska Kinga | Zendy; Neumann Beate | Zendy; Schoeller Wolfgang W. | Zendy; Stammler HansGeorg | Zendy

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[2,6‐(Trip) 2 H 3 C 6 ](Cp*)Si: A Stable Monomeric Arylsilicon(II) Compound

Author(s) -

Jutzi Peter,

Leszczyńska Kinga,

Neumann Beate,

Schoeller Wolfgang W.,

Stammler HansGeorg

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805749

Subject(s) - aryl , monomer , substituent , terphenyl , silylene , crystallography , chemistry , ligand (biochemistry) , group (periodic table) , stereochemistry , silicon , organic chemistry , alkyl , polymer , biochemistry , receptor

Si takes a rest : A bulky σ‐bound terphenyl substituent and a π‐bound Cp* ligand enable the isolation and full characterization of the first aryl‐substituted, monomeric silicon(II) compound 1 , which can be regarded as the “resting state” of a true silylene containing a σ‐bound Cp* group. The conformation of the aryl group prevents aryl–Si π back‐bonding.

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