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Reactions of Tin(II) Hydride Species with Unsaturated Molecules
Author(s) -
Jana Anukul,
Roesky Herbert W.,
Schulzke Carola,
Döring Alexander
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805595
Subject(s) - tin , hydride , lone pair , chemistry , molecule , metal , crystallography , combinatorial chemistry , medicinal chemistry , organic chemistry
If anything can, tin can : The tin(II) hydride species [LSnH] (L=HC{CMeN(2,6‐ i Pr 2 C 6 H 3 )} 2 ) reacts with various compounds containing unsaturated CO, CC, or CN bonds, which results in simultaneous transfer of hydrogen and {LSn} to the organic substrates and elegantly generates new tin(II) compounds. These unique stannylene compounds incorporate a lone pair of electrons that is suitable for complexation with transition‐metal species.