Reactions of Tin(II) Hydride Species with Unsaturated Molecules | Zendy

Jana Anukul | Zendy; Roesky Herbert W. | Zendy; Schulzke Carola | Zendy; Döring Alexander | Zendy

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Reactions of Tin(II) Hydride Species with Unsaturated Molecules

Author(s) -

Jana Anukul,

Roesky Herbert W.,

Schulzke Carola,

Döring Alexander

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805595

Subject(s) - tin , hydride , lone pair , chemistry , molecule , metal , crystallography , combinatorial chemistry , medicinal chemistry , organic chemistry

If anything can, tin can : The tin(II) hydride species [LSnH] (L=HC{CMeN(2,6‐ i Pr 2 C 6 H 3 )} 2 ) reacts with various compounds containing unsaturated CO, CC, or CN bonds, which results in simultaneous transfer of hydrogen and {LSn} to the organic substrates and elegantly generates new tin(II) compounds. These unique stannylene compounds incorporate a lone pair of electrons that is suitable for complexation with transition‐metal species.

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