A Chiral Concave‐Bound Cyclopentadienyl Iron Complex of Sumanene | Zendy

Sakane Hiroyuki | Zendy; Amaya Toru | Zendy; Moriuchi Toshiyuki | Zendy; Hirao Toshikazu | Zendy

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A Chiral Concave‐Bound Cyclopentadienyl Iron Complex of Sumanene

Author(s) -

Sakane Hiroyuki,

Amaya Toru,

Moriuchi Toshiyuki,

Hirao Toshikazu

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805567

Subject(s) - cyclopentadienyl complex , atropisomer , stacking , desymmetrization , chemistry , stereochemistry , crystallography , ligand (biochemistry) , ring (chemistry) , enantioselective synthesis , organic chemistry , catalysis , biochemistry , receptor

Great bowls of fire : The rotation of the cyclopentadienyl (Cp) ring is restricted in two concave‐bound monoalkyl‐substituted [CpFe(η 6 ‐sumanene)] + “π‐bowl” complexes (see picture). The asymmetric stacking of atropisomers was observed with a MeCpFe complex in the solid state and the chiral ( S )‐ s BuCpFe complex showed magnetic and optical desymmetrization of the sumanene ligand, which is the first example of a chiral complex of a π‐bowl ligand.

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