Shape‐Selective Interception by Hydrocarbons of the O 2 ‐Derived Oxidant of a Biomimetic Nonheme Iron Complex | Zendy

Mukherjee Anusree | Zendy; Martinho Marlène | Zendy; Bominaar Emile L. | Zendy; Münck Eckard | Zendy; Que Lawrence | Zendy

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Shape‐Selective Interception by Hydrocarbons of the O 2 ‐Derived Oxidant of a Biomimetic Nonheme Iron Complex

Author(s) -

Mukherjee Anusree,

Martinho Marlène,

Bominaar Emile L.,

Münck Eckard,

Que Lawrence

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805342

Subject(s) - chemistry , oblate spheroid , boron , interception , ligand (biochemistry) , medicinal chemistry , stereochemistry , inorganic chemistry , photochemistry , organic chemistry , biochemistry , physics , receptor , ecology , atomic physics , biology

Picky ferryl : The complex [Fe(Tp Ph 2)(BF)] (Tp Ph 2=hydrotris(3,5‐diphenylpyrazolyl)borate; BF=benzoylformate) reacts with O 2 to generate an oxidant (see picture; O red, pink; Fe yellow; N blue; C gray; H white) that oxidizes added hydrocarbons shape‐selectively. Discrimination derives from a cleft formed by two phenyl groups of the Tp Ph 2ligand, favoring oblate spheroidal substrates.

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