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Functional Molecular Flasks: New Properties and Reactions within Discrete, Self‐Assembled Hosts
Author(s) -
Yoshizawa Michito,
Klosterman Jeremy K.,
Fujita Makoto
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805340
Subject(s) - laboratory flask , nanotechnology , modular design , molecule , chemistry , reactivity (psychology) , self assembly , materials science , chemical physics , organic chemistry , computer science , operating system , medicine , alternative medicine , pathology
Abstract Insider dealing : Self‐assembled hosts applied as “molecular flasks” can alter and control the reactivity and properties of molecules encapsulated within their well‐defined, confined spaces. A variety of functional hosts of differing sizes, shapes, and utility have been prepared by using the facile and modular concepts of self‐assembly.The application of self‐assembled hosts as “molecular flasks” has precipitated a surge of interest in the reactivity and properties of molecules within well‐defined confined spaces. The facile and modular synthesis of self‐assembled hosts has enabled a variety of hosts of differing sizes, shapes, and properties to be prepared. This Review briefly highlights the various molecular flasks synthesized before focusing on their use as functional molecular containers—specifically for the encapsulation of guest molecules to either engender unusual reactions or unique chemical phenomena. Such self‐assembled cavities now constitute a new phase of chemistry, which cannot be achieved in the conventional solid, liquid, and gas phases.