Direct Observation of Contact Ion‐Pair Formation in Aqueous Solution | Zendy

Antonio Mark R. | Zendy; Nyman May | Zendy; Anderson Travis M. | Zendy

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Direct Observation of Contact Ion‐Pair Formation in Aqueous Solution

Author(s) -

Antonio Mark R.,

Nyman May,

Anderson Travis M.

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805323

Subject(s) - aqueous solution , radius of gyration , small angle x ray scattering , ion , scattering , polyoxometalate , gyration , caesium , chemistry , radius , chemical physics , materials science , crystallography , inorganic chemistry , physics , optics , polymer , geometry , organic chemistry , mathematics , catalysis , computer security , computer science

Nude or neutralized? Small‐angle X‐ray Scattering (SAXS) measurements provide direct observation of contact ion pairing between the [Nb 6 O 19 ] 8− polyoxometalate and its eight charge‐balancing cesium cations in aqueous solution. The radius of gyration ( R g ) for Cs 8 [Nb 6 O 19 ] and [Nb 6 O 19 ] 8− is shown.

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