Premium
Heteroanalogues of PCBM: N‐Bridged Imino‐PCBMs for Organic Field‐Effect Transistors
Author(s) -
Yang Changduk,
Cho Shinuk,
Heeger Alan J.,
Wudl Fred
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805228
Subject(s) - bridging (networking) , cycloaddition , fullerene , chemistry , butyric acid , azide , materials science , stereochemistry , organic chemistry , catalysis , computer science , computer network
Crossing the bridge : Two isomeric iminofullerenes, [5,6]‐open azafulleroid 1 and [6,6]‐closed aziridinofullerene 2 , were prepared by cycloaddition of an organic azide to C 60 . These “azalogues” enable the study of the effects of the bridging atom in a fullerene cage, that is, C 60 ‐like (5,6‐open) versus PCBM‐like (6,6‐closed), as a function of their π systems (PCBM=[6,6]‐phenyl‐C 61 ‐butyric acid methyl ester).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom