Premium
The Copper‐Catalyzed Decarboxylative Coupling of the sp 3 ‐Hybridized Carbon Atoms of α‐Amino Acids
Author(s) -
Bi HaiPeng,
Zhao Liang,
Liang YongMin,
Li ChaoJun
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805122
Subject(s) - intermolecular force , copper , amino acid , catalysis , nitrogen , carbon fibers , chemistry , coupling (piping) , decarboxylation , stereochemistry , organic chemistry , molecule , materials science , biochemistry , composite number , metallurgy , composite material
Joined at the Cs : A novel intermolecular decarboxylative C sp 3C sp 3, C sp 3C sp 2, and C sp 3C sp coupling catalyzed by CuBr and using α‐amino acids as starting materials has been developed (see scheme). Various functionalized nitrogen‐containing compounds were obtained by this method.