Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia–Borane | Zendy

Käß Martina | Zendy; Friedrich Anja | Zendy; Drees Markus | Zendy; Schneider Sven | Zendy

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Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia–Borane

Author(s) -

Käß Martina,

Friedrich Anja,

Drees Markus,

Schneider Sven

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805108

Subject(s) - ammonia borane , ruthenium , dehydrogenation , bifunctional , chemistry , borane , reactivity (psychology) , catalysis , ligand (biochemistry) , ammonia , medicinal chemistry , bifunctional catalyst , combinatorial chemistry , photochemistry , organic chemistry , biochemistry , medicine , alternative medicine , receptor , pathology

G“Ru”vy reactivity : The new ruthenium(II) complex having cooperative PNP enamido ligand A reversibly activates two equivalents H 2 under reversible hydrogenation of amido ( B ) and amino ( C ) complexes. B exhibits the highest reported activities in the dehydrocoupling of ammonia–borane.

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