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Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia–Borane
Author(s) -
Käß Martina,
Friedrich Anja,
Drees Markus,
Schneider Sven
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805108
Subject(s) - ammonia borane , ruthenium , dehydrogenation , bifunctional , chemistry , borane , reactivity (psychology) , catalysis , ligand (biochemistry) , ammonia , medicinal chemistry , bifunctional catalyst , combinatorial chemistry , photochemistry , organic chemistry , biochemistry , medicine , alternative medicine , receptor , pathology
G“Ru”vy reactivity : The new ruthenium(II) complex having cooperative PNP enamido ligand A reversibly activates two equivalents H 2 under reversible hydrogenation of amido ( B ) and amino ( C ) complexes. B exhibits the highest reported activities in the dehydrocoupling of ammonia–borane.