Adducts of NH 3  with the Conformers of Glycidol: A Rotational Spectroscopy Study | Zendy

Giuliano Barbara M. | Zendy; Melandri Sonia | Zendy; Maris Assimo | Zendy; Favero Laura B. | Zendy; Caminati Walther | Zendy

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Adducts of NH 3 with the Conformers of Glycidol: A Rotational Spectroscopy Study

Author(s) -

Giuliano Barbara M.,

Melandri Sonia,

Maris Assimo,

Favero Laura B.,

Caminati Walther

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200805104

Subject(s) - glycidol , conformational isomerism , adduct , hydrogen bond , spectroscopy , molecule , chemistry , crystallography , organic chemistry , physics , catalysis , quantum mechanics

Two locks accept the same master key : Two different complexes of ammonia with two different conformers of glycidol have been characterized by Fourier transform microwave spectroscopy (see picture; gray C, blue N, red O, white H). In both complexes NH 3 is linked to the alcohol molecule through an OH⋅⋅⋅N (stronger) and an NH⋅⋅⋅O (weaker) hydrogen bond. Structural and energetic features of the hydrogen bonds are given.

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