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CF Activation at Rhodium Boryl Complexes: Formation of 2‐Fluoroalkyl‐1,3,2‐Dioxaborolanes by Catalytic Functionalization of Hexafluoropropene
Author(s) -
Braun Thomas,
Ahijado Salomon Marcel,
Altenhöner Kai,
Teltewskoi Michael,
Hinze Silke
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200805041
Subject(s) - rhodium , catalysis , hydride , surface modification , chemistry , cleavage (geology) , borylation , bond cleavage , polymer chemistry , medicinal chemistry , photochemistry , organic chemistry , materials science , metal , aryl , alkyl , fracture (geology) , composite material
Fluorinated building blocks by CF bond cleavage : Catalytic CF activation reactions that give novel dioxaborolanes have been developed (see scheme). The reactions proceed at room temperature, and catalytic intermediates are presumably rhodium hydride and boryl species.