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A Thermally and Hydrolytically Stable Microporous Framework Exhibiting Single‐Chain Magnetism: Structure and Properties of [Co 2 (H 0.67 bdt) 3 ]⋅20 H 2 O
Author(s) -
Ouellette Wayne,
Prosvirin Andrey V.,
Whitenack Kelly,
Dunbar Kim R.,
Zubieta Jon
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200804805
Subject(s) - microporous material , magnetism , hydrothermal circulation , crystallography , chemistry , solvation , hydrothermal synthesis , materials science , hydrogen , chain (unit) , void (composites) , chemical engineering , condensed matter physics , organic chemistry , physics , molecule , composite material , engineering , astronomy
Fixing a hole : Hydrothermal chemistry has been exploited in the preparation of a 3D framework material exhibiting 48 % accessible void volume and 1.5 % hydrogen uptake by weight at 120 kPa (see picture). The title compound also exhibits single‐chain magnetic behavior and reversible changes in magnetic properties upon solvation and desolvation.