Early Main‐Group Metal Catalysts for the Hydrogenation of Alkenes with H 2 | Zendy

Spielmann Jan | Zendy; Buch Frank | Zendy; Harder Sjoerd | Zendy

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Early Main‐Group Metal Catalysts for the Hydrogenation of Alkenes with H 2

Author(s) -

Spielmann Jan,

Buch Frank,

Harder Sjoerd

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200804657

Subject(s) - catalysis , metathesis , hydride , metal , transition metal , double bond , polymerization , chemistry , bar (unit) , group (periodic table) , materials science , polymer chemistry , organic chemistry , physics , meteorology , polymer

Transition‐metal‐free hydrogenation of alkenes can be carried out with simple organocalcium catalysts (20 bar H 2 , 20 °C). Both steps in the proposed catalytic cycle, hydride addition to the double bond and σ‐bond metathesis with H 2 , have been confirmed. Alkenes sensitive to polymerization are also hydrogenated in good yields.

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