A Stable Radical Species from Facile Oxygenation of meso‐Free 5,10,20,25‐Tetrakis(pentafluorophenyl)‐Substituted [26]Hexaphyrin(1.1.1.1.1.1) | Zendy

Koide Taro | Zendy; Kashiwazaki Gengo | Zendy; Suzuki Masaaki | Zendy; Furukawa Ko | Zendy; Yoon MinChul | Zendy; Cho Sung | Zendy; Kim Dongho | Zendy; Osuka Atsuhiro | Zendy

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A Stable Radical Species from Facile Oxygenation of meso‐Free 5,10,20,25‐Tetrakis(pentafluorophenyl)‐Substituted [26]Hexaphyrin(1.1.1.1.1.1)

Author(s) -

Koide Taro,

Kashiwazaki Gengo,

Suzuki Masaaki,

Furukawa Ko,

Yoon MinChul,

Cho Sung,

Kim Dongho,

Osuka Atsuhiro

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200804570

Subject(s) - chemistry , planar , radical , oxygenation , photochemistry , stereochemistry , organic chemistry , computer science , ecology , computer graphics (images) , biology

A stable radical : The title compound 1 has been synthesized as the first example of a meso‐free variant and characterized as a strongly aromatic macrocycle with a spectacles‐like planar conformation. The incorporation of free meso positions is promising for the exploration of novel structural and electronic properties.

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