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Unprecedented and Differently Applicable Pentagonal Units in a Dynamic Library: A Keplerate of the Type {(W)W 5 } 12 {Mo 2 } 30
Author(s) -
Schäffer Christian,
Merca Alice,
Bögge Hartmut,
Todea Ana Maria,
Kistler Melissa L.,
Liu Tianbo,
Thouvenot René,
Gouzerh Pierre,
Müller Achim
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200804496
Subject(s) - molybdenum , tungstate , pentagonal bipyramidal molecular geometry , crystallography , molybdenum oxide , physics , materials science , crystal structure , chemistry , metallurgy
Magic pentagons : Exploitation of versatile pentagonal units/ligands has previously led to giant molybdenum oxide based curved species, including spherical Keplerates. Similar methodology is now also applicable to the related tungstate scenario (see corresponding basic central pentagonal unit in green).