Drastic Acceleration of Phosphine/Phosphite Incorporation into a Tetrahydrido Ruthenium/Osmium Complex, and One‐way Ruthenium to Osmium Migration of a Phosphorus Ligand | Zendy

Kameo Hajime | Zendy; Nakajima Yumiko | Zendy; Suzuki Hiroharu | Zendy

Premium

Drastic Acceleration of Phosphine/Phosphite Incorporation into a Tetrahydrido Ruthenium/Osmium Complex, and One‐way Ruthenium to Osmium Migration of a Phosphorus Ligand

Author(s) -

Kameo Hajime,

Nakajima Yumiko,

Suzuki Hiroharu

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200804482

Subject(s) - ruthenium , osmium , phosphine , ligand (biochemistry) , chemistry , medicinal chemistry , phosphorus , acceleration , catalysis , organic chemistry , physics , biochemistry , receptor , classical mechanics

Unequal partners : Reactions of complexes of the form [Cp*M(μ‐H) 4 M′Cp*] ( 1 : M=M′=Ru; 2 : M=Ru, M′=Os; 3 : M= M′=Os) with P(OMe) 3 provide evidence of kinetic and thermodynamic heterometallic effects. Heterometallic complex 2 induces selective addition of P(OMe) 3 to the Ru center in an accelerated reaction. Moreover, the incorporated P(OMe) 3 migrates unidirectionally from Ru to Os owing to the formation of a strong OsP bond.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research