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Synthesis and Electrochemical Reduction of a Ruthenium Complex Bearing an N , N ‐Bis[(benzo[ g ][1,5]naphthyridin‐2‐yl)methyl]propane‐2‐amine Ligand as an NAD + /NADH‐Type Redox Site
Author(s) -
Kimura Masahiro,
Tanaka Koji
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200804404
Subject(s) - ruthenium , chemistry , electrochemistry , amine gas treating , propane , ligand (biochemistry) , medicinal chemistry , pivalic acid , combinatorial chemistry , stereochemistry , organic chemistry , catalysis , electrode , biochemistry , receptor
Going slightly NADH : The electrochemical reduction of [Ru(bbnma)(bpy)(CO)](PF 6 ) 2 (bbnma= N , N ‐bis[(benzo[ g ][1,5]naphthyridin‐2‐yl)methyl]propane‐2‐amine, bpy=2,2′‐bipyridine) in the presence of pivalic acid gave [Ru(bbnmaH 4 )(bpy)(CO)](PF 6 ) 2 , the NADH‐type product of a four‐electron reduction.