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Solid‐State Scrolls from Hierarchical Self‐Assembly of T‐Shaped Rod–Coil Molecules
Author(s) -
Hong DongJe,
Lee Eunji,
Jeong Haemi,
Lee Jeongkyu,
Zin WangCheol,
Nguyen Trung Dac,
Glotzer Sharon C.,
Lee Myongsoo
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200804307
Subject(s) - rod , electromagnetic coil , molecule , materials science , plane (geometry) , solid state , coiled coil , crystallography , optics , chemistry , physics , geometry , engineering , electrical engineering , mathematics , medicine , alternative medicine , organic chemistry , pathology , biochemistry
On a roll : Attachment of flexible coils to the middle of a rigid rod generates T‐shaped rod–coil molecules that self‐assemble into layers that roll up to form filled cylindrical and hollow tubular scrolls, depending on the coil length, in the solid state (see picture); the rods are arranged parallel to the layer plane.