Supertetrahedral and Bi‐supertetrahedral Cages: Synthesis, Structures, and Magnetic Properties of Deca‐ and Enneadecametallic Cobalt(II) Clusters | Zendy

Lisnard Laurent | Zendy; Tuna Floriana | Zendy; Candini Andrea | Zendy; Affronte Marco | Zendy; Winpenny Richard E. P. | Zendy; McInnes Eric J. L. | Zendy

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Supertetrahedral and Bi‐supertetrahedral Cages: Synthesis, Structures, and Magnetic Properties of Deca‐ and Enneadecametallic Cobalt(II) Clusters

Author(s) -

Lisnard Laurent,

Tuna Floriana,

Candini Andrea,

Affronte Marco,

Winpenny Richard E. P.,

McInnes Eric J. L.

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200804147

Subject(s) - cobalt , crystallography , cage , magnetization , chemistry , materials science , stereochemistry , inorganic chemistry , physics , magnetic field , mathematics , combinatorics , quantum mechanics

Magnetic cage : Simple cobalt(II) diketonates react with triols under solvothermal conditions to give a family of compounds based on supertetrahedral cage structures: a regular and a distorted {Co II 10 } species, and a bi‐supertetrahedral {Co II 19 } species. Magnetic studies show unusual properties, such as nonvanishing magnetization below 12 K, which until now have only been detected in a family of {Ni 10 } clusters.

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