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Highly Active Dizinc Catalyst for the Copolymerization of Carbon Dioxide and Cyclohexene Oxide at One Atmosphere Pressure
Author(s) -
Kember Michael R.,
Knight Paul D.,
Reung Palarp T. R.,
Williams Charlotte K.
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803896
Subject(s) - atmosphere (unit) , catalysis , cyclohexene oxide , oxide , copolymer , carbon dioxide , cyclohexene , ligand (biochemistry) , chemistry , carbon fibers , combinatorial chemistry , organic chemistry , computer science , physics , algorithm , meteorology , polymer , biochemistry , receptor , composite number
Low‐pressure catalyst : A novel dizinc complex ( 1 ) having a macrocyclic ancillary ligand shows remarkable activity for the copolymerization of carbon dioxide and cyclohexene oxide, at only one atmosphere of CO 2 . TON=turnover number; TOF=turnover frequency.