Hydrogenation of Arenes by Dual Activation: Reduction of Substrates Ranging from Benzene to C 60  Fullerene under Ambient Conditions | Zendy

Deshmukh Ravindra R. | Zendy; Lee Ji Woong | Zendy; Shin Ueon Sang | Zendy; Lee Jin Yong | Zendy; Song Choong Eui | Zendy

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Hydrogenation of Arenes by Dual Activation: Reduction of Substrates Ranging from Benzene to C 60 Fullerene under Ambient Conditions

Author(s) -

Deshmukh Ravindra R.,

Lee Ji Woong,

Shin Ueon Sang,

Lee Jin Yong,

Song Choong Eui

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803850

Subject(s) - benzene , fullerene , ionic liquid , ionic bonding , chemistry , bar (unit) , benzene derivatives , photochemistry , aromaticity , hydrogen , combinatorial chemistry , organic chemistry , catalysis , molecule , ion , chemical synthesis , physics , biochemistry , meteorology , in vitro

Tackling aromaticity : The title reaction was accomplished by simultaneous activation of molecular hydrogen and the aromatic substrate by Pd/C and a Lewis acidic ionic liquid, respectively. Even benzene and C 60 fullerene were hydrogenated under ambient conditions (1 bar of H 2 at room temperature). An ionic hydrogenation mechanism (see scheme) is supported by characterization of a stabilized arenium intermediate.

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