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Fabrication of Two‐Dimensional Polymer Arrays: Template Synthesis of Polypyrrole between Redox‐Active Coordination Nanoslits
Author(s) -
Yanai Nobuhiro,
Uemura Takashi,
Ohba Masaaki,
Kadowaki Yu,
Maesato Mitsuhiko,
Takenaka Mikihito,
Nishitsuji Shotaro,
Hasegawa Hirokazu,
Kitagawa Susumu
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803846
Subject(s) - polypyrrole , redox , polymerization , polymer , nanotechnology , fabrication , pyrrole , materials science , coordination polymer , combinatorial chemistry , computer science , chemistry , organic chemistry , composite material , medicine , alternative medicine , pathology , metallurgy
A redox sandwich : Oxidative and intercalative polymerization of pyrrole was conducted within the nanoslits of a layered open coordination framework containing redox‐active sites. The resulting polypyrrole, which can be isolated from the host framework, exists as stacked sheet polymer objects, the orientation and morphology of which are directly related to those of the original coordination‐polymer template.