A 3 (U 2 O 4 )(Ge 2 O 7 ) (A=Rb, Cs): Mixed‐Valence Uranium(V,VI) Germanates | Zendy

Lin ChiaHui | Zendy; Lii KwangHwa | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

A 3 (U 2 O 4 )(Ge 2 O 7 ) (A=Rb, Cs): Mixed‐Valence Uranium(V,VI) Germanates

Author(s) -

Lin ChiaHui,

Lii KwangHwa

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803658

Subject(s) - valence (chemistry) , octahedron , uranium , tetragonal crystal system , crystallography , tetrahedron , hydrothermal circulation , mineralogy , chemistry , materials science , crystal structure , geology , metallurgy , organic chemistry , seismology

An unusual mix : The first mixed‐valence uranium(V,VI) germanates are synthesized under hydrothermal conditions. The structure of A 3 (U 2 O 4 )(Ge 2 O 7 ) (A=Rb, Cs) contains chains of corner‐sharing U 5+ O 6 octahedra (purple) and U 6+ O 6 tetragonal bipyramids (yellow), which are interconnected by GeO 4 tetrahedra (green) to form a 3D framework (see picture; A blue).

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research