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Heteroatom‐Stabilized Chiral Framework of Aluminophosphate Molecular Sieves
Author(s) -
Song Xiaowei,
Li Yi,
Gan Lin,
Wang Zhuopeng,
Yu Jihong,
Xu Ruren
Publication year - 2009
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803578
Subject(s) - heteroatom , crystallography , materials science , molecular sieve , ring (chemistry) , tetrahedron , chemistry , organic chemistry , catalysis
Intrinsically chiral : The compounds (C 4 H 12 N) 2 [M 2 Al 10 P 12 O 48 ] (denoted MAPO‐CJ40; M=Co, Zn) were solvothermally synthesized. Their structure contains one‐dimensional helical 10‐ring channels enclosed by double‐helical ribbons of the same handedness made of the edge‐sharing of 6‐rings along the 2 1 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.