Heteroatom‐Stabilized Chiral Framework of Aluminophosphate Molecular Sieves | Zendy

Song Xiaowei | Zendy; Li Yi | Zendy; Gan Lin | Zendy; Wang Zhuopeng | Zendy; Yu Jihong | Zendy; Xu Ruren | Zendy

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Heteroatom‐Stabilized Chiral Framework of Aluminophosphate Molecular Sieves

Author(s) -

Song Xiaowei,

Li Yi,

Gan Lin,

Wang Zhuopeng,

Yu Jihong,

Xu Ruren

Publication year - 2009

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803578

Subject(s) - heteroatom , crystallography , materials science , molecular sieve , ring (chemistry) , tetrahedron , chemistry , organic chemistry , catalysis

Intrinsically chiral : The compounds (C 4 H 12 N) 2 [M 2 Al 10 P 12 O 48 ] (denoted MAPO‐CJ40; M=Co, Zn) were solvothermally synthesized. Their structure contains one‐dimensional helical 10‐ring channels enclosed by double‐helical ribbons of the same handedness made of the edge‐sharing of 6‐rings along the 2 1 screw axis. The framework is intrinsically chiral and exhibits a new zeotype structure.

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