Self‐Assembly of a Nanoscopic Pt 12 Fe 12  Heterometallic Open Molecular Box Containing Six Porphyrin Walls | Zendy

Bar Arun Kumar | Zendy; Chakrabarty Rajesh | Zendy; Mostafa Golam | Zendy; Mukherjee Partha Sarathi | Zendy

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Self‐Assembly of a Nanoscopic Pt 12 Fe 12 Heterometallic Open Molecular Box Containing Six Porphyrin Walls

Author(s) -

Bar Arun Kumar,

Chakrabarty Rajesh,

Mostafa Golam,

Mukherjee Partha Sarathi

Publication year - 2008

Publication title -

angewandte chemie international edition

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 1433-7851

DOI - 10.1002/anie.200803543

Subject(s) - porphyrin , ferrocene , nanoscopic scale , materials science , information retrieval , nanotechnology , computer science , chemistry , organic chemistry , electrochemistry , electrode

Box it up! Self‐assembly of 5,10,15,20‐tetrakis(4‐pyridyl)porphyrin with two equivalents of cis ‐[(dppf)Pt(OTf) 2 ] (dppf=1,1′‐bis(diphenylphosphino)ferrocene; OTf=CF 3 SO 3 − ) yielded the first open molecular box containing six porphyrin walls (see scheme) and an internal open void volume of around 43 550 Å 3 .

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