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Self‐Assembly of a Nanoscopic Pt 12 Fe 12 Heterometallic Open Molecular Box Containing Six Porphyrin Walls
Author(s) -
Bar Arun Kumar,
Chakrabarty Rajesh,
Mostafa Golam,
Mukherjee Partha Sarathi
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803543
Subject(s) - porphyrin , ferrocene , nanoscopic scale , materials science , information retrieval , nanotechnology , computer science , chemistry , organic chemistry , electrochemistry , electrode
Box it up! Self‐assembly of 5,10,15,20‐tetrakis(4‐pyridyl)porphyrin with two equivalents of cis ‐[(dppf)Pt(OTf) 2 ] (dppf=1,1′‐bis(diphenylphosphino)ferrocene; OTf=CF 3 SO 3 − ) yielded the first open molecular box containing six porphyrin walls (see scheme) and an internal open void volume of around 43 550 Å 3 .