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Self‐Assembly of a Heteropolyoxopalladate Nanocube: [Pd II 13 As V 8 O 34 (OH) 6 ] 8−
Author(s) -
Chubarova Elena V.,
Dickman Michael H.,
Keita Bineta,
Nadjo Louis,
Miserque Frédéric,
Mifsud Maria,
Arends Isabel W. C. E.,
Kortz Ulrich
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803527
Subject(s) - palladium , crystallography , ion , cluster (spacecraft) , oxide , chemistry , arsenic , materials science , atomic physics , physics , catalysis , biochemistry , organic chemistry , computer science , programming language
Not like the others : A molecular palladium oxide cluster was formed by self‐assembly of palladium(II) and arsenic(V) using mild reaction conditions. The resulting heteropolypalladate [Pd II 13 As V 8 O 34 (OH) 6 ] 8− has a distorted cubic shape and edge lengths of about 1 nm. The thirteen Pd II ions retain four‐coordinate square‐planar geometry, in marked contrast to all other known discrete polyoxometalates.