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A Synthetic Analogue of Rieske‐Type [2Fe‐2S] Clusters
Author(s) -
Ballmann Joachim,
Albers Antonia,
Demeshko Serhiy,
Dechert Sebastian,
Bill Eckhard,
Bothe Eberhard,
Ryde Ulf,
Meyer Franc
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803418
Subject(s) - chemistry , combinatorial chemistry , stereochemistry
Copycat : An accurate synthetic model for Rieske type [2Fe‐2S] cluster has been prepared that emulates structural and spectroscopic features of the natural protein sites, including the characteristic low g av value in the EPR spectra of the reduced [2Fe‐2S] + species. The picture shows the crystal structure of the molecule (C gray, Fe red, N blue, S yellow), its EPR spectrum after reduction (bottom) and its Mössbauer spectrum (top).