Premium
A Synthetic Analogue of Rieske‐Type [2Fe‐2S] Clusters
Author(s) -
Ballmann Joachim,
Albers Antonia,
Demeshko Serhiy,
Dechert Sebastian,
Bill Eckhard,
Bothe Eberhard,
Ryde Ulf,
Meyer Franc
Publication year - 2008
Publication title -
angewandte chemie international edition
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 1433-7851
DOI - 10.1002/anie.200803418
Subject(s) - chemistry , combinatorial chemistry , stereochemistry
Copycat : An accurate synthetic model for Rieske type [2Fe‐2S] cluster has been prepared that emulates structural and spectroscopic features of the natural protein sites, including the characteristic low g av value in the EPR spectra of the reduced [2Fe‐2S] + species. The picture shows the crystal structure of the molecule (C gray, Fe red, N blue, S yellow), its EPR spectrum after reduction (bottom) and its Mössbauer spectrum (top).
Accelerating Research
Robert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom
Address
John Eccles HouseRobert Robinson Avenue,
Oxford Science Park, Oxford
OX4 4GP, United Kingdom